A new approach to internal Lewis pairs featuring a phosphenium acid and a pyridine base.
نویسندگان
چکیده
A bis(imino)acenaphthene (BIAN) ligand containing a pendant Lewis base has been used as a new framework to support a N-heterocyclic phosphenium cation (NHP). Reactivity studies demonstrate the ability of the ligand to act as a Lewis base, while the phosphorus centre provides a Lewis acidic site, giving new opportunities in NHP chemistry.
منابع مشابه
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ورودعنوان ژورنال:
- Dalton transactions
دوره 39 45 شماره
صفحات -
تاریخ انتشار 2010